Automatically open a specific workbook or template when you …
https://support.microsoft.com/en-us/office/automatically-open-a-specific-workbook-or-template-when-you-start-excel-be9cddc1-a148-4cbf-8f3b-779df08957a3
WEBClick File > Excel Options > Advanced. Under General, in the At Startup, open all files in box, type the full path of the folder that you want to use as the alternate startup folder. Note: Because Excel will try and open every file in the alternate startup folder, make sure that you specify a folder that contains only files that Excel can open.
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